by Cuenca, Teresa, Filice, Marco and Palomo, Jose M
Abstract:
Palladium nanoparticles enzyme aggregate (PANEA) were prepared from Candida antarctica B lipase and palladium salt by precipitation and subsequent in situ Pd nanoparticle formation. This heterogeneous catalyst was successfully used for the Suzuki-Miyaura cross-coupling reaction between bromobenzene with different phenylboronic acid derivatives under mild reaction conditions and using low Pd amount. The nanocatalyst exhibited the highest catalytic activity in a mixture of methanol/water (1:1), obtaining good to excellent product yields from the cross-coupling reaction. A variety of functional groups were accepted and the catalyst was recycled 4 times without activity loss.
Reference:
Palladium nanoparticles enzyme aggregate (PANEA) as efficient catalyst for Suzuki-Miyaura reaction in aqueous media. (Cuenca, Teresa, Filice, Marco and Palomo, Jose M), In Enzyme and microbial technology, volume 95, 2016.
Bibtex Entry:
@article{Cuenca:2016fd,
author = {Cuenca, Teresa and Filice, Marco and Palomo, Jose M},
title = {{Palladium nanoparticles enzyme aggregate (PANEA) as efficient catalyst for Suzuki-Miyaura reaction in aqueous media.}},
journal = {Enzyme and microbial technology},
year = {2016},
volume = {95},
pages = {242--247},
month = dec,
affiliation = {Departamento de Biocat{'a}lisis, Instituto de Cat{'a}lisis (CSIC), c/Marie Curie 2, Cantoblanco, Campus UAM, 28049 Madrid, Spain.},
doi = {10.1016/j.enzmictec.2016.01.014},
pmid = {27866622},
language = {English},
rating = {0},
date-added = {2016-12-12T13:04:19GMT},
date-modified = {2018-03-16T13:14:13GMT},
abstract = {Palladium nanoparticles enzyme aggregate (PANEA) were prepared from Candida antarctica B lipase and palladium salt by precipitation and subsequent in situ Pd nanoparticle formation. This heterogeneous catalyst was successfully used for the Suzuki-Miyaura cross-coupling reaction between bromobenzene with different phenylboronic acid derivatives under mild reaction conditions and using low Pd amount. The nanocatalyst exhibited the highest catalytic activity in a mixture of methanol/water (1:1), obtaining good to excellent product yields from the cross-coupling reaction. A variety of functional groups were accepted and the catalyst was recycled 4 times without activity loss.},
url = {http://linkinghub.elsevier.com/retrieve/pii/S014102291630014X},
uri = {url{papers3://publication/doi/10.1016/j.enzmictec.2016.01.014}}
}